Two copies of the same book, printed a century apart, can look decades different on the shelf. One keeps its paper white and its pages flexible, the other has gone yellow and brittle at the edges. The difference is chemistry, and it starts with the pulp.
Lignin is the problem
Wood is held together by lignin, the woody binder around the cellulose fibres. Chemical pulping, the kraft process used for most book and office paper, dissolves most of that lignin away and leaves long, strong cellulose fibres. Mechanical pulping, used for newsprint and cheap groundwood, keeps much more of the lignin because it grinds the wood rather than cooking it. Lignin is not stable. Over years it oxidises, and the paper yellows and loses strength. Newsprint is the familiar example: it turns brown within days in sunlight and embrittles far sooner than a book page.






